Homespun refers to plain cloth but is often used to describe something as rustic.
Catercorner is used as both an adverb and an adjective to describe things that are situated in a diagonal or oblique position. this is a less common variant of kitty-corner.
A hummock is a small round hill or mound.
Leonine means relating to resembling a lion.
Bodacious means very good or impressive.